Short Answer Type

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Why it is not possible to separate the enantiomers?


It is not possible to separate the enantiomers due to rapid nitrogen inversion. This inversion does not involve bond breaking or bond formation.
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Suggest chemical reactions for the following conversions:
n-hexanitrite to 1-aminopentane.
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Write one chemical reaction each to illustrate the following:
A coupling reaction of a diazonium salt.

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Suggest chemical reactions for the following conversions:
p-chloroaniline to p-chlorobenzylamine.
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Illustrate each of the following with an example of reaction:
Sandmeyer reaction.

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Arrange the following set of amines in order of increasing pKa values:


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Arrange the following set of amines in order of increasing pKa values:




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Account for the following:
Aqueous solution of methyl amine reacts with iron (III) chloride to precipitate iron (III) hydroxide.

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Illustrate  the following with an example of reaction:
Diazotization reaction.

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Write one chemical reaction to explain an acylation reaction.

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