Amines

Short Answer Type

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Why are aryl diazonium ions more stable than alkyl diazonium ions?

Aryl diazonium ions  are more stable than R-N2+ due to resonance. Aryl diazonium ions have more contributing  structure than alkyl diazonium ions. Hence, aryl diazonium is more stable.
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    Explain what is meant by the 'protection of the amino group'.?

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    Show by means of equations how an amide may be converted into an amine containing the same number of carbon atoms.

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    Why does bromination of aniline, even under very mild conditions give 2, 4, 6- tribromo aniline instantaneously?

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    Long Answer Type

    Draw all possible isomers of a benzene containing compound with molecular formula C7H9N. Write their IUPAC names. Explain their reaction towards nitrous acid.
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    Short Answer Type

    How is benzene diazonium chloride obtained?

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    How would you protect the amino group during the nitration of an aromatic amino compound? Give chemical equations.
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    Write the structure of the products of the following reactions:
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    An organic compound (A) with IMF C4H11N, capable of being resolved into optical isomers gives a base soluble product with benzene sulphonyl chloride. What is the structure and IUPAC name of (A)? What happens when this compound (A) is treated with ethanoyl chloride?

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    Show by means of equations how an amide may be converted into an amine containing one carbon atom less than the amide.

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