Short Answer Type

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Describe the theory associated with the radius of an atom as it loses on electron.


Loss of electron: When a neutral atom loses one electron to form a cation, its radius decreases. In the cation, the nuclear charge remains the same as that of the parent atom but the number of electrons becomes less. Since the same nuclear charge now attracts the lesser number of electrons, therefore, the force of attraction of the nucleus on the electrons of all the shells increases. i.e. effective nuclear charge per electron increases in the cation and hence the size of the cation decreases. Thus






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Long Answer Type

What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.
(i) F-  (ii) Ar    (iii) Mg2+   (iv) Rb+ 

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Short Answer Type

Give the formula of a species which will be isoelectronic with the following atoms or ions:
(i) Na2+ 
(ii) Cl

(iii) Ca2+ 
(iv) Rb
+.

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Which of the following species will have the largest and the smallest size?
Mg, Mg2+, Al, Al3+.

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Describe the theory associated with the radius of an atom as it gains on electron.
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Arrange the following ions in order of increasing size:
Be2+, Cl-, S2-, Na+, Mg2+, Br-.

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Long Answer Type

In each of the following pairs,  which species has a larger size? Explain.
(i) K or K+ 
(ii) Br or Br
- 
(iii) O
2- or F
(iv) Li+ or Na+ 
(v) P or As
(vi) Na
+ or Mg2+

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What do you understand by iso-electronic ions? In iso-electronic ions, the value of ionic radius decreases with the increase in atomic number. Explain.
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Short Answer Type

For each of the following pairs, state which one is larger in size and why?
(i) Na, Na+     (ii) Br, Br-    (iii) Br, I
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Long Answer Type

Consider the following species : N3-, O2-, F-, Na+, Mg2+ and Al3+

(a) What is common in them?

(b) Arrange them in the order of increasing ionic radii. 

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