Short Answer Type

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Nitrogen and phosphorus have high value of ionisation enthalpies. Explain.


The electronic configurations of N (Z = 7) and P(Z = 15) are:



Both these elements have the configurations in which all the orbitals of the same sub-level are exactly half-filled. Such an arrangement gives extra stability to the atom. As a result, the removal of electron becomes difficult and hence they have high value of ionisation enthalpies.
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Among the elements of second period i.e. from Li to Ne, pick out the elements:

(a) with the highest first ionisation enthalpy
(b) with the highest electronegativity
(c) with the largest atomic radius
(d) which is the most reactive non-metal
(e) which is the most reactive metal ?

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Long Answer Type

The IE1,  of carbon, is more than that of boron while its IE2 value is smaller. Explain.

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Short Answer Type

How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium? 

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Long Answer Type

Which of the following pairs of elements would you expect to have lower first ionisation enthalpy? Explain your answer:

(a) Cl or F

(b) Cl or S

(c) K or Ar

(d) Kr or Xe.

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Short Answer Type

The first (IE1) and second (IE2) ionisation enthalpies (kJ mol-1) of a few elements by Roman numerals are as shown:

  IE1 IE2
i 2372 IE2
ii 520 7300
iii 900 1760
iv 1680 380

which of the above elements is likely to be:
(i) a reactive metal
(ii) a reactive non-metal
(iii) a noble gas
(iv) a metal that forms a stable binary halide of the formula AX3 (X = halogen).

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The first ionization enthalpy values (in kJ mol-1) of group 13 elements are:
B       Al      Ga      In        Tl
801    577   579    558    589
How would you explain this deviation from the general trend?

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Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or different? Justify your answer. 
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Be and Mg have high value of ionisation enthalpies. Explain.

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Arrange the following in order of increasing ionisation enthalpies and assign reason:

(i) K+, Ar, Cl-    
(ii) Fe, Fe2+, Fe3+

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