Short Answer Type

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Among the elements of second period i.e. from Li to Ne, pick out the elements:

(a) with the highest first ionisation enthalpy
(b) with the highest electronegativity
(c) with the largest atomic radius
(d) which is the most reactive non-metal
(e) which is the most reactive metal ?


The elements of the second period are:
Li, Be, B, C, N, O, F, Ne

(a) The element with highest first ionisation enthalpy: Neon (Ne).

(b) The element with highest electronegativity: Fluorine (F).

(c) The element with largest atomic radius: Lithium (Li).

(d) The most reactive non-metal: Fluorine (F).

(e) The most reactive metal: Lithium (Li).

 
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Long Answer Type

The IE1,  of carbon, is more than that of boron while its IE2 value is smaller. Explain.

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Short Answer Type

The first ionization enthalpy values (in kJ mol-1) of group 13 elements are:
B       Al      Ga      In        Tl
801    577   579    558    589
How would you explain this deviation from the general trend?

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Nitrogen and phosphorus have high value of ionisation enthalpies. Explain.

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How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium? 

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Be and Mg have high value of ionisation enthalpies. Explain.

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The first (IE1) and second (IE2) ionisation enthalpies (kJ mol-1) of a few elements by Roman numerals are as shown:

  IE1 IE2
i 2372 IE2
ii 520 7300
iii 900 1760
iv 1680 380

which of the above elements is likely to be:
(i) a reactive metal
(ii) a reactive non-metal
(iii) a noble gas
(iv) a metal that forms a stable binary halide of the formula AX3 (X = halogen).

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Long Answer Type

Which of the following pairs of elements would you expect to have lower first ionisation enthalpy? Explain your answer:

(a) Cl or F

(b) Cl or S

(c) K or Ar

(d) Kr or Xe.

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Short Answer Type

Arrange the following in order of increasing ionisation enthalpies and assign reason:

(i) K+, Ar, Cl-    
(ii) Fe, Fe2+, Fe3+

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Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or different? Justify your answer. 
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