Multiple Choice Questions

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The size of the iso-electronic species Cl-, Ar and Ca2+ is affected by:

  • nuclear charge

  • Prinicpal quantum number of valence shell

  • azimuthal quantum number of valence shell

  • electron-electron interaction in the outer orbitals


A.

nuclear charge

Isoelectronic species contain same number of shells so their size is effected by the nuclear charge.


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The equation used to represents the electron gain enthalpy is

  • X(g) + e- → X-(g)

  • X(s) + e- → X-(g)

  • X(g) → X+(g) + e-

  • X(s) → X+(g) + e-


What is the atomic number of the element with symbol Uus?

  • 117

  • 116

  • 115

  • 114


The increasing order of the first ionisation enthalpies of the elements B, P, S and F is 

  • B < S < P < F

  • F < S < P < B

  • P < S < B < F

  • B < P < S < F


The electronic configuration of 59Pr ( praseodimium) is

  • [54Xe] 4f25d16s2

  • [54Xe] 4f15d16s2

  • [54Xe] 4f36s2

  • [54Xe] 4f35d2


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Among the following species, the diamagnetic molecule is:

  • B2

  • O2

  • CO

  • NO


The electronic configuration of Eu (Atomic no.63), Gd (Atomic no. 64) and Tb (Atomic no. 65) are

  • [Xe]4f6 5d1 6s2, [Xe] 4f7 5d1 6s2 and [Xe] 4f9  6s2 

  • [Xe] 4f6 5d1 6s2 , [Xe] 4f7 5d1 6s2 and [Xe] 4f8 5d1 6s2 

  • [Xe] 4f7  6s2, [Xe] 4f7 5d1 6s2 and [Xe] 4f9 6s2 

  • [Xe] 4f7  6s2, [Xe] 4f7 5d1 6s2 and [Xe] 4f9 6s2 

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Among the following, the isoelectronic specie (s) is/are

(i)  O2-, F-, Na+, Mg2+

(ii) Na+, Mg+, Al3+, F-

(iii) N3-,  O2-, F-, Ne

  • (i) and (ii)

  • (i), (ii) and (iii)

  • (ii) and (iii)

  • (i) and (iii)


The element having greatest difference between its first and second ionization energies, is

  • K

  • Ca

  • Ba

  • Sc


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An element in +2 oxidation state has 24 electrons. The atomic number of the element and the number of unpaired electrons in it respectively are

  • 24 and 4

  • 26 and 4

  • 24 and 2

  • 26 and 5


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