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Why is geometrical isomerism not possible in tetrahedral complexes having two different types of unidentate ligands coordinated with the central metal ion ?


Tetrahedral complexes do not show geometrical isomerism because the relative positions of the unidentate ligands attached to the central metal atom are the some with respect to each other.


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Which isomer of  [CoCl2(en)2]+ does not show optical isomerism?

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Draw structures of geometrical isomers of [Fe(NH3)2(CN)4].

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Specify which out of the following complex structures exhibit geometrical isomerism:
(a) Linear,   (b) Square planar,  (c) Tetrahedral, (d) Octahedral.

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Give an example of neutral bidentate ligand.
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What are the basic difference between the two geometrical isomers – cis/trans or fac/ mor?
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Give two examples of positive mono-denate ligands. 

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Write all isomers of [Co(C2O4)3]3–.

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Give an example of hexadentate ligand.

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Write the chemical formula of:
(i) Sodium tetrahydridoborate(III).
(ii) Tetrahydroxo zincate(II) ion.

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