Coordination Compounds

Short Answer Type

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Write all isomers of [Co(C2O4)3]3–.

This will show two optical isomers.





Fig. Isomers of [Co(C2O4)3]3–.
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    Why is geometrical isomerism not possible in tetrahedral complexes having two different types of unidentate ligands coordinated with the central metal ion ?

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    Give an example of hexadentate ligand.

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    Which isomer of  [CoCl2(en)2]+ does not show optical isomerism?

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    Give two examples of positive mono-denate ligands. 

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    What are the basic difference between the two geometrical isomers – cis/trans or fac/ mor?
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    Write the chemical formula of:
    (i) Sodium tetrahydridoborate(III).
    (ii) Tetrahydroxo zincate(II) ion.

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    Draw structures of geometrical isomers of [Fe(NH3)2(CN)4]–.

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    Give an example of neutral bidentate ligand.
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    Specify which out of the following complex structures exhibit geometrical isomerism:
    (a) Linear,   (b) Square planar,  (c) Tetrahedral, (d) Octahedral.

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