Coordination Compounds

Short Answer Type

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Give the name of a bidentate ligand.

When a ligand can bind through two donor atoms as in H2NCH2CH2NH2 (ethane-1,2-diamine) or
C2O42– (oxalate), the ligand is said to be bidentate ligand.

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    Write down the IUPAC names of the following compounds:

    (i) [CO(NH3)5ONO ]Cl2     
    (ii) K3[    Cr(CN)6]

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    Write the IUPAC name for  [Cr(NH3)5 CO3]Cl.

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    Which of the two is more stable K4[Fe(CN)6] or K3[Fe(CN)6].

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    Explain why chelating complex is more stable than unchelated complex?

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    Draw cis- and trans-isomers of [Pt(NH3)2Cl2].

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    [Fe(CN)6]3– is weakly paramagnetic while [Fe(CNO)6]4– is diamagnetic, why?
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    Write IUPAC name of K3[Fe(C2O4)3].

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    Give two complexes which are used in medicines.

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    A coordination compound has the formula CoCl3.4NH3. It does not liberate NH3 but forms a precipitate of AgCl on treatment with AgNO3 solution. Write the structure and IUPAC name of the complex.

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