Short Answer Type

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Square planar complexes with coordination number of 4 exhibit geometrical isomerism whereas tetrahedral complexes do not. Why?


In tetrahedral complexes, the relative position of atoms with respect to each other is same, thus these do not show geometrical isomerism. Square planar complexes show cis, trans-isomerism.
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Square planar complexes do not show optical isomerism. Why?

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Name the ionisation isomer of [Cr(H2O)5Br]SO4.

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What is the significance of Δ0?

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[Cu(CN)4]2+ is more stable complex than [Cu(NH3)4]+. Why?
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Write the IUPAC name of [Ni(H2O)6] (ClO4)2.

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Give the name of following complex using IUPAC norms:
[Co(en)2(ONO)Cl]Cl. 

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Write IUPAC name of the complex  [Co(NH3)5SCN]Cl2.

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Why does [CoF6]3– give a high spin complex?

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Give the IUPAC name of [NH4]3 [Co(ONO)6].

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