Short Answer Type

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What is the oxidation state of the metal in the following coordiantion compound?
(i) Ni in Ni(CO)4    (ii) Co in [Co(CO) 4]


(i) The oxidation state of nickel is zero.

Ni =x
CO=0

therefore oxidation state is 0

(ii) The oxidation state of cobalt is –1.

Co=x
CO=0
anion=+1

x+0=1

Therefore oxidation state is 1.


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What is the charge on the complex of Pt2+ in which the ligands are - one water molecule, one pyridine molecule and one ethylene diamine molecule?

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How many moles of ions are formed when one mole of the complex, [Co(NH3)4Cl2]Cl is completely dissociated into ions?

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Write down the IUPAC names of the following compounds:
(i) [Co(NH3)5ONO]Cl2,    (ii) K3[Cr(CN)6]        
(iii) [Cr(NH3)5CO3]Cl
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If the geometry of [PtCl4]2– is square planar, which orbitals of Pt are involved in the bonding?

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Write formula of the following complexes:
(i) Penta amine chlorocobalt(II)
(ii) Lithium tetrahydro aluminate(III).

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Name the type of isomerism that occurs in complexes in which both cation and anion are complex ions.

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Which of the following will give white precipitate with AgNO3 solution:
[Pt(NH3)2Cl4],   K[Pt(NH3)Cl5],    [Pt(NH3)3 Cl3]Cl?

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Write the formula of the first f-block organometallic synthesised.

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Which part of the d-block metals forms stable metal carbonyls?

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