Short Answer Type

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Write the formula for the following complex:


Pentaamminenitrito-o-Cobalt (III)


Formula: [Co(NH3)5(ONO)]2+

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Long Answer Type

Draw the structure of the following compounds:
(a) cis-[CrCl2(OX)2]3–    (b) [Ni(CN)4]2–  
(c) [Fe(CN)6]3–               (d) Meridional [CrCl3(NH3)3]+
(e) trans-[PtCl2(en)2]2+.

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Write the correct formulae for the following coordination compounds:
(a)    CrCl3.6H2O (violet, with 3 chloride ions/unit formula)
(b)    CrCl3.6H2O (light green, with 2 chloride ion/unit formula)
(c)    CrCl3.5H2O (dark green, with 1 chloride ion/unit formula)


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Short Answer Type

On the basis of crystal field theory, write the electronic configuration for d4 ion if ∆o < P ?

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A coordination compound has the formula CoCl3.4NH3. It does not liberate ammonia but forms a precipitate with AgNO3. Write the structure and IUPAC name of the complex compound.

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Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].

(At.no. of Ni = 28)

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Write down the IUPAC name of the following complex:


[Cr(NH3)2Cl2(en)]Cl    (en = ethylenediamine)

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Explain the following terms:
(a) coordination number    
(b) counter ions.

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Draw the geometrical isomers of complex [Pt(NH3)2Cl2]? 

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Which of the following is a more stable complex and why?

 (i) [Co(NH3)6]3+

 (ii) [Co(en)3]3+

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