Short Answer Type

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Which compound in each of the following pairs will react faster in SN2 reaction with HO?
(a) CH3—Br or CH3I
(b) (CH3)3 Cl or CH3Cl2
(c)  CH2=CHBr or CH2 = CH—CH2Br.


(a) CH3I (Due to its bigger size thus better leaving group.

(b) CH3Cl (As the size of the alkyl group increases the reactivity decreases and CH3Cl have less number of alkyl group.

(c) CH2 = CHBr (Due to lesser number of alkyl group).

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Write the structure of the following compounds halides.
(a) 2-Bromo-2-methyl propane
(b) 2-chloro-2-methyl propane
(c) 2-Bromo-3-methylbutane.

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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene:
Cyclo hexyl methyl bromide.
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A hydrocarbon C5H12 gives only one chlorination product. Identify the hydrocarbon.

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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene:
2-Chloro-2-methylbutane
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What happens when chlorobenzene is heated with sodium and chloromethane in ether?
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Arrange the following to the increasing order of boiling point
(i)

(ii) CH3CHCH2CH3

(iii) CH3CH2CH2CH2Br

(iv) (CH3)3 C—Cl




   

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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene:
2, 2, 3-trimethyl-3-bromopentane.
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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene:
1-bromo-1 methyl cyclohexane.
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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene:
3-bromo-1-ene.
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