Arrange the following to the increasing order of boiling point (i)
(ii) CH3CHCH2CH3
(iii) CH3CH2CH2CH2Br
(iv) (CH3)3 C—Cl
The boiling point haloalkanes decrease with increase in branching. Therefore the increasing order of boiling point is,
(iv) < (i) < (ii) < (iii).
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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene: 1-bromo-1 methyl cyclohexane.
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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene: 2-Chloro-2-methylbutane
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A hydrocarbon C5H12 gives only one chlorination product. Identify the hydrocarbon.
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Write the structure of the following compounds halides. (a) 2-Bromo-2-methyl propane (b) 2-chloro-2-methyl propane (c) 2-Bromo-3-methylbutane.
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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene: 3-bromo-1-ene.
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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene: 2, 2, 3-trimethyl-3-bromopentane.
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What happens when chlorobenzene is heated with sodium and chloromethane in ether?
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Which compound in each of the following pairs will react faster in SN2 reaction with HO–? (a) CH3—Br or CH3I (b) (CH3)3 Cl or CH3Cl2 (c) CH2=CHBr or CH2 = CH—CH2Br.
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Predict all the alkenes that would be formed by dihydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene: Cyclo hexyl methyl bromide.
