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Dry gaseous hydraulic acid and not their aqueous solutions are used to prepare alkyl halides from alkenes.


Dry hydrogen halides are stronger acids and better electrophiles than the H3O+ ion formed in their aqueous solutions. Moreover, H2O is a nucleophile and may react with Rto form an alcohol instead of alkyl halide.


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What are the structure of the possible isomes of dichloroethane? Which of them will have zero dipole movement?

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Start from chlorobenzene how will you obtain Phenol.

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Arrange the following compounds in increasing order of SN1 , respectively.

(CH3)3CCI, C6H5(CH3)2Cl, CH3CH2CH2Cl

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Arrange the following alkyl halides in the decreasing order of SN2 reactivity.



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Iodoform is obtained by the reaction of acetone with hypoidodide ion and not with iodide ion.

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How will you prepare 1-bromo propane from 2-bromo propane?

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How will you prepare 1-bromo propane from 1-chloro propane?

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Start from chlorobenzene how will you obtain Toluene.

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How will you prepare 1, 2-ethane diol from 1-chloro ethane?

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