Short Answer Type

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Which would undergo SN2 reaction faster in the following pair and why?


Sn2 reactions are bimolecular with simultaneous bond-making and bond-breaking steps. Primary alkyl halides prefer to undergo SN2 reactions than tertiary alkyl halides because of less steric hindrance experienced by the approaching nucleophile.

 Hence, out of the given pair, (CH3 –CH 2 – Br ) would undergo SN2 reaction faster.

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Give reasons:

The presence of nitro group (–NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.

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Long Answer Type

Give the laboratory preparation of the Iodoform and its mechanism?
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Short Answer Type

Which alkyl halide from the following pair is chiral and undergoes faster SN2 reaction?

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Out of SN1 and SN2, which reaction occurs with

(a) Inversion of configuration

(b) Racemisation 

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Give reasons:

Racemic mixture is optically inactive.

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Write the IUPAC name of


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n-Butyl bromide has higher boiling point than t-butyl bromide.

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Write the resonance structure of chlorobenzene. Why is chlorobenzene less reactive than chloromethane towards nucleophiles?
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Draw the structure of major monohalo product in each of the following reactions: 
i) 


ii) 

 

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