Hydrocarbons

Short Answer Type

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What is Saytzeff’s rule? Explain it with an example. 

Certain haloalkanes can undergo elimination in two different ways giving a mixture of two products. In such reactions, the preferred product is the more highly substituted alkene (i.e. the alkene having lesser number of hydrogens on the doubly bonded carbon atoms). This generalisation is known as Saytzeff’s rule.
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    What happens when butan-2-ol is heated with concentrated H2SO4. Account for the product formed.

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    What happens when 2-Bromobutane is heated with alcoholic KOH. Account for the product formed.

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    Which of the following compounds will show cis-trans isomerism?

    (i)(CH3)2C = CH-C2H5
    (ii) CH2 = CBr2
    (iii) C2H5CH = CH-CH2
    (iv) CH3CH = CClCH3 

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    Out of the two - trans-but-2-ene and cis-but-1-ene, which is more stable and why

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    Alkanes and alkynes do not exhibit geometrical isomerism. Explain. 

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    Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?

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    Draw cis and trans isomers of the following compounds. Also, write their IUPAC names:

    (i) CHCl = CHCl

    (ii) C2H5CCH3 = CCH3C2H5 

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    Long Answer Type

    How will you explain that there exists two varieties of 1, 2,-dichloroethene while there is only one type of 1, 2-dichloroethane?

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    Short Answer Type

    Which of the following compounds would show geometrical isomerism? Draw the isomeric structures to support your answer:
    (i) But-2-ene
    (ii) Pent-1-ene
    (iii) 2-Methyl-But -2-ene
    (iv) 3, 4-Dimethyl-hex-3-ene
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