Multiple Choice Questions

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The quality of diesel is expressed by

  • octane number

  • cetane number

  • antiknock compound

  • presence of additives


B.

cetane number

(a) Octane numberis used to express the quality of petrol and gasoline.

(b) Cetane numberis used to express the quality of diesel. It is defined as the percentage of cetane (by volume) in a mixture of cetane (n-hexadecane) and α-methylnaphthalene which has the same ignition properties as the fuel under consideration.

(c) Antiknock compounds such as TEL (tetraethyl lead) is used to improve the quality of gasoline.

(d) Additives are also used to improve the quality of gasoline.


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When petroleum is heated gradually, the first batch of vapours evolved will be rich in

  • kerosene oil

  • diesel oil

  • lubricating oil

  • petroleum ether


An alkyl bromide is formed as the major product on reaction of 3-methyl-2-butene with hydrobromic acid under thermodynamic conditions. Which of the following is the correct IUPAC name of this product?

  • 2-bromo-3-methylbutane

  • 1-bromo-3-methylbutane

  • 2-bromo-2-methylbutane

  • 1-bromo-3-methyl-2-butene


Which organic compound is an electrolyte ?

  • CH3Cl

  • HCOOH

  • CH3OH

  • C6H12O6


Which one of the following represents the major product of the reaction of benzene with 2, 2-dimethylpropyl chloride in presence of anhydrous aluminium chloride?

  • 2, 2-dimethylpropylbenzene

  • 1, 1-dimethylpropylbenzene

  • 1, 2-dimethylpropylbenzene

  • 1, 2-dimethyl-1-propenylbenzene


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Octane number of petrol can be improved by admixing it with which of the following chemicals?

  • Et4Pb

  • CH3OC(CH3)3

  • Both (a) and (b)

  • Pyrene


An alkene having molecular formula, C6H10 gives  OHC(CH2)4CHO, on ozonolysis. The alkene is

  • hexene-1

  • hexene-2

  • cyclohexene

  • 1-methylcyclohexene-1


The correct name for the following hydrocarbon is

   

  • tricycle [4.1.0] heptane

  • bicyclo [5.2.1] heptane

  • bicyclo [4.1.0] heptane

  • bicyclo [4.1.0] hexane


The petrol, octane number of which is 80, has

  • 20% n-heptane + 80% iso-octane

  • 20% n-heptane + 80% n-octane

  • 80% n-heptane + 20% iso-octane

  • 80% n-heptane+ 20% n-octane


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The number of isomeric alkanes having the molecular formula C5H12 is

  • Three

  • Five

  • nine

  • Thirty two


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