Will you prefer to polymerize acrylo-nitrile under anionic or cationic polymerization conditions? Explain your choice.
We will prefer to polymerise acrylonitrile (CH2 = CHCN) under anionic polymerization conditions.
In this case, the active centre of the propagating species is negatively charged. Hence, it occurs easily with monomers containing electron-withdrawing groups such as nitrile.
Differentiate between chain growth and step growth polymerization. Give the structural formula one polymer of each type.
Why is cationic polymerization preferred in case of vinylic monomers containing electron donating groups?
Differentiate between elastomers and fibres on the basis of inter-molecular forces. Give one structural formula of each type of polymers.
What are the different ways of initiating addition polymerization? Describe one of them for polymerising vinyl chloride.
How are polymers classified into different categories on the basis of intermolecular forces? Give one example of a polymer of each of these categories.