Long Answer Type

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Why does styrene undergo anionic polymerization easily?


Anionic Addition Polymerization: Styrene undergoes anionic polymerization easily because C6H5 group in styrene is electron withdrawing. It involves following steps:

(i) Chain initiation step:


(ii) Chain propagation step:



(iii) Chain termination step:

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How does the presence of benzoquinone inhibit the free radical polymerization of a vinyl derivative?
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Short Answer Type

Write the names and molecular structure of the monomers of the following:
(i) Natural rubber (ii) Neoprene.

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Long Answer Type

Explain how does 1, 3-butadiene polymerize by different routes?
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What are linear polymer and branched chain polymers? How do these differ from own linked polymers?

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Give the monomers and uses of each of the following addition polymers:
(a) Polyethylene    

(b) Polypropylene       

(c) Polystyrene.

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Elaborate the structure of natural rubber.

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Short Answer Type

Explain with suitable examples:
(i)    Natural polymers
(ii)   Synthetic polymers.

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Write the names and structures of the monomers of the following polymers:
(i) Polystyrene (ii) Neoprene.

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Define a polymer. Write the monomer used for the preparation of dacron. Mention a use of it.

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