Short Answer Type

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Name the oxometal anions of the first series of the transition metals in which the metal exhibits the oxidation state equal to its group number. 


Name of oxometal anion

Name of metal with oxidation state

Group no. to which metal belong

1.    CrO42–
(chromate ion)

2.    MnO4
(permanganate ion)
3.Vanadate 

Cr in +6 state of oxidation
Mn in +7 state

oxidation state +5

6th group of periodic table
7th group

 
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Long Answer Type

Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?  
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To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with example.
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Short Answer Type

What may be the stable oxidation state of the transition element with the following d electron configurations in the ground state of their atoms: 3d3, 3d5, 3d8 and 3d4
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Long Answer Type

What are the characteristics of the transition elements and why are they called transition elements? Which of the d-block elements may not be regarded as the transition elements? 
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What is lanthanoid contraction? What are the consequences of lanthanoid contraction?
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Short Answer Type

Write down the electronic configuration of:
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(iv) Mn2+ (v) Pm3+(vi) Ce4+
 (vii) Lu2+ (viii) Th4+
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Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their +3 state?
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What is the effect of increasing pH in K2Cr2O7, solution?

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