Short Answer Type

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Why the transition element series show fewer oxidation states at their extreme ends e.g., Sc, Ti, Ni and Cu.


At the extreme ends of the series, either too few electrons present.
In case of (Sc, Ti) therevery few electron thus show lower oxidation state.
In case of  (Ni, Cu) number eletron is more thus all electron paired and due to this it shows less oxidation state.
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Long Answer Type

What are paramagnetic and ferromagnetic substances? Account for the paramagnetic character of transition metal compounds. How does the paramagnetic character of the bivalent ions of first transition metal series vary from titanium (Z = 22) to copper (Z = 29)?
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Short Answer Type

In what way are the observed oxidation states of the lanthanides related to their electronic configurations?

 
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Why are the absorption bonds of lanthanoids narrow
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How is the variability in the oxidation states of transition metals different from that of the nontransition metals? Illustrate with examples.

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Assign reasons for the following:
The enthalpies of atomisation of transition metals are high.

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Long Answer Type

Describe the general characteristics of the transition elements with special reference to their tendency to:
(i)    Exhibit paramagnetism.
(ii)    Form complex compounds.
(iii)    Their catalytic behaviour.

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Short Answer Type

What are inner transition elements? Write their general electronic configuration.
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Why are transition metals able to form alloys?

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What is the reason for the decreasing tendency to form divalent cation across the series as indicated by the decreasing E°M2+ /M values?
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