Multiple Choice Questions

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Identify the statement which is not correct regarding CuSO4

  • It react with KI to give iodine

  • It react with KCl to give Cu2Cl2

  • It react with NaOH and glucose to give Cu2O.

  • It gives CuO on strongly heating in air.


B.

It react with KCl to give Cu2Cl2

CuSO4 reacts with KI to give white precipitate of Cu2I2 and to evolve I2. But it does not react with KCl in the same way. 


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The effective atomic number of cobalt in the complex [Co(NH3)6]+ is

  • 36

  • 24

  • 33

  • 30


Sterling silver is

  • AgNO3

  • Ag2S

  • Alloy of 80% Ag+ 20% Cu

  • AgCl


'925 fine silver' means an alloy of
  • 7.5% Ag and 92.5% Cu

  • 92.5% Ag and 7.5% Cu

  • 80% Ag and 20% Cu

  • 90% Ag and 10% Cu


Which of the following is not a characteristic of transition elements?

  • Variable oxidation states

  • Formation of coloured compounds

  • Formation of interstitial compounds

  • Natural radioactivity


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The correct formula of the complex tetraammineaquachlorocobalt (III) chloride is

  • [Cl(H2O)(NH3)4Co]Cl

  • [CoCl(H2O)(NH3)4]Cl

  • [Co(NH3)4(H2O)Cl]Cl

  • [CoCl(H2O)(NH3)4]Cl2


Assertion (A): Cu2+ and Cd2+ are separated by first adding KCN solution and then passing H-S gas.
Reason (R): KCN reduces Cu2+ to Cu+ and forms a complex with it.
The correct answer is

  • Both (A) and (R) are true and (R) is the correct explanation of (A)

  • Both (A) and (R) are true but (R) is not the correct explanation of (A)

  • (A) is true but (R) is not true

  • (A) is not true but (R) is true


Which one of the following sets correctly represents the increase in the paramagnetic property of the ions?

  • Cu2+ > V 2+ > Cr2+ > Mn2+

  • Cu2+ < Cr2+  < V 2+ < Mn2+

  • Cu2+ < V 2+ < Cr2+ < Mn2+

  • V 2+ < Cu2+  < Cr2+ < Mn2+


Across the lanthanide series, the basicity of the lanthanide hydroxides

  • increases

  • decreases

  • first increases and then decreases

  • first decreases and then increases


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Transition metals usually exhibit highest oxidation states in their

  • chlorides

  • fluorides

  • bromides

  • iodides


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