Multiple Choice Questions

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Which one of the following shows highest magnetic moment?

  • Fe2+

  • Co2+

  • Cr3+

  • Ni2+


A.

Fe2+

The paramagnetism or magnetic moment produced due to spin of electrons or unpaired electrons is expressed in terms of Bohr magneton (BM) or μB and given by 

Magnetic moment (μ) =√[n(n+2)]BM

where n is the number of unpaired electron, in species. Thus, greater is the number of unpaired electron is an ion greater is its paramagnetic nature.

Ion electronic configuration No. of  unpaired e- s
Cr3+ d3 3
Fe2+ d6 4
Co2+ d7 3
Ni2+ d8 2

As Fe2+ ion has maximum number of unpaired electrons, thus it has highest magnetic moment.


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Which of the following has the maximum number of unpaired 'd' electrons?

  • Zn2+

  • Fe2+

  • Ni3+

  • Cu+


In chromite ore, the oxidation number of iron, and chromium are respectively

  • +3,+2

  • +3,+6

  • +2,+6

  • +2,+3


The spin only magnetic moment of Mn4+ ion is nearly

  • 3BM

  • 6BM

  • 4BM

  • 5BM


Mercury is a liquid metal because

  • it has a completely filled s orbital

  • it has a small atomic size

  • it has a completely filled d orbital that prevents d-d overlapping of orbitals

  • it has a completely filled d orbital that causes d-d overlapping


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The electronic configuration of Cu2+ ion is

  • [Ar] 3d8 4s1

  • [Ar] 3d9 4s0

  • [Ar] 3d7 4s2

  • [Ar] 3d8 4s0


In chromite ore, the oxidation number of iron and chromium are respectively

  • +3, +2

  • +3, +6

  • +2, +6

  • +2, +3


Which of the following is a negatively charged bidentate ligand?

  • Cyano

  • Ethylene diamine

  • Acetato

  • Dimethyl glyoximato


In a transition series, with increase in atomic-number, the paramagnetism

  • increases gradually

  • decreases gradually

  • first increases to a maximum and then decreases

  • first decreases to a minimum and then increases


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An element with atomic number 21 is a

  • halogen

  • representative element

  • transition element

  • alkali metal


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