Multiple Choice Questions

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XeF2 is isostructural with 

  • TeF2

  • ICl-2

  • SbCl3

  • SbCl3


B.

ICl-2

Species having the same number of bond pairs and lone pairs are isostructural (have same structure)

Species

 lp+bp

 Structure

 XeF2

  4 lp +2bp

Linear 

 TeF2

 2lp +2bp

 Angular or V-shape 

 ICl2-

 4lp +2bp

 Liner

 BaCl2

 0 lp +2bp

 (linear paper) Cl-Ba-Cl 

 Thus, XeF2, is isostructural with ICl2- and BaCl2.

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Which of the following oxide is amphoteric?

  • SnO2

  • CaO2

  • SiO2

  • SiO2

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Which of the following statements is not valid for oxoacids of phosphorus? 

  • Orthophosphoric acid is used in the manufacture of triple superphosphate

  • Hypophosphorous acid is a diprotic acid
  • All oxoacids contain tetrahedral four coordinated phosphorus

  • All oxoacids contain tetrahedral four coordinated phosphorus

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In Which of the following arrangement, the given sequence is not strictly according to the property indicated against it ? 

  • HF < HCl< HBr < HI : increasing acidic strength

  • H2O < H2S < H2Se < H2Te : increasing pKa values.

  • NH3 < PH3 < AsH3 < SbH : increasing acidic character

  • NH3 < PH3 < AsH3 < SbH : increasing acidic character

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Oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively

  • +3, +5, +4

  • +5, +3, +4

  • +5, +4,+3

  • +5, +4,+3

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The stability of +1 oxidation state among Al, Ga, In and TI increases in the sequence

  • Ga<In< Al<Tl

  • Al<Ga<In<Tl

  • Tl<In<Ga<Al

  • Tl<In<Ga<Al

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Which of the following is a polar molecule?

  • BF3

  • SF4

  • SiF4

  • SiF4

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Which one of the following molecules contains no pi -bond?

  • CO2

  • H2O

  • SO2

  • SO2

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Strong reducing behaviour of H3PO4 is due to

  • the presence of one -OH group and two P-H bonds

  • high electron gain enthalpy of phosphorous 

  • the high oxidation state of phosphorus

  • the high oxidation state of phosphorus

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The variation of the boiling point of the hydrogen halides in the order HF >  HI > HBr > HCl. What explains the higher boiling point of hydrogen fluoride?

  • The electronegativity of fluorine is much higher than for other elements in the group

  • There is strong hydrogen bonding between HF molecules

  • The bond energy of HF molecules is greater than in other hydrogens halides

  • The bond energy of HF molecules is greater than in other hydrogens halides

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