Multiple Choice Questions

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The correct statement is

  • The earlier members of lanthanoid series resemble calcium in their chemical properties.

  • The extent of actinoid contraction is almost the same as lanthanoid contraction.

  • In general, lanthanoid and actinoids do not show variable oxidation states.

  • Ce4+ in aqueous solution is not known.


A.

The earlier members of lanthanoid series resemble calcium in their chemical properties.

The earlier members of lanthanoid series resemble calcium in some of their chemical properties. e g., Hydroxide of both of them are ionic and basic.


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The electronic configuration of Cu2+ ion is

  • [Ar] 3d8 4s1

  • [Ar] 3d9 4s0

  • [Ar] 3d7 4s2

  • [Ar] 3d8 4s0


Which one of the following shows highest magnetic moment?

  • Fe2+

  • Co2+

  • Cr3+

  • Ni2+


The composition of "copper matte" is

  • Cu2S + FeS

  • Cu2S + Cu2O

  • Cu2S + FeO

  • Cu2O + FeS


The electronic configuration of Gd2+ is (atomic number of Gd is 64).

  • [Xe]4f8

  • [Xe]4f7

  • [Xe]4f7 5d16s2

  • [Xe]4f7 5d1


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When a brown compound of Mn (A) is treated with HCl, it gives a gas (B). The gas (B) taken in excess reacts with NH3 to give; an explosive compound (C). The compounds A, B and C respectively are

  • A - MnO2; B - Cl2; C - NCl3

  • A - MnO; B - Cl2; C - NH4Cl

  • A - Mn3O4; B - Cl2; C - NCl3

  • A - MnO3; B - Cl2; C - NCl2


Mn2+ compounds are more stable than Fe2+ compounds towards oxidation to their +3 state, because

  • Mn2+ is more stable with high 3rd ionisation energy

  • Mn2+ is bigger in size

  • Mn2+ has completely filled d-orbital

  • Mn2+ does not exist


The bivalent metal ion having maximum paramagnetic behaviour among the first transition series elements is

  • Mn2+

  • Cu2+

  • Sc2+

  • Cu+


In a transition series, with increase in atomic-number, the paramagnetism

  • increases gradually

  • decreases gradually

  • first increases to a maximum and then decreases

  • first decreases to a minimum and then increases


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Which of the following is a negatively charged bidentate ligand?

  • Cyano

  • Ethylene diamine

  • Acetato

  • Dimethyl glyoximato


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