Multiple Choice Questions

Advertisement

The shape of gaseous SnCl2 is

  • Tetrahedral

  • Linear

  • Angular

  • T-shape


C.

Angular

Total no. of valence electron for Sn = 4
Total no. of valence electron for Cl = 7
Thus total number of valence electron for SnCl2 = 4 + 7 x 2 = 18
Bond pair = 2
Number of electrons used to complete the octets and duet = 8 x 2 = 16
No. of lone pair = 1

SnCl2 has sp2 hybridisation with one lone pair of electrons. Thus has angular shape. 


Advertisement

Name the gas that can readily decolourises acidified KMnO4 solution

  • CO2

  • SO2

  • NO2

  • NO2

1440 Views

Actinides exhibit larger number of oxidation state than that of corresponding lanthanides. The reason behind this aspect is

  • lesser energy difference between 5f and 6d-orbitals than between 4f and 5d-orbitals

  • larger atomic size of actinides than the lanthanides

  • more energy difference between 5f and 6d orbitals than between 4f and 5d-orbitals

  • greater reactive nature of the actinides than the lanthanides


Which one of the following ions is the most stable in aqueous solution?

  • Cr3+

  • V3+

  • Ti3+

  • Ti3+


The reason for greater range of oxidation states in actinoids is attributed to

  • The radioactive nature of actinoids

  • Actinoid contraction

  • 5f, 6d and 7s levels having comparable energies

  • 5f, 6d and 7s levels having comparable energies

1045 Views

Advertisement

The correct increasing order of ionic radii of the following Ce3+, La3+, Pm3+ and Yb3+ is 

  • Yb3+ < Pm3+< Ce3+<La3+

  • Ce3+< Yb3+<Pm3+<La3+

  • Yb3+< Pm3+< La3+<Ce3+

  • Pm3+ < La3+< Ce3+ < Yb3+


More the number of oxidation states are exhibited by the actinoids than by the lanthanoids. The main reason for this is:

  • more energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals

  • the lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals

  • the greater metallic character of the lanthanoids than that of the corresponding actinoids

  • the greater metallic character of the lanthanoids than that of the corresponding actinoids

503 Views

[CuCl4]2- exists while [CuI4]2- does not exist, because

  • I- is stronger reductant than Cl-

  • I- is weaker reductant than Cl-

  • I- is stronger oxidant than Cl-

  • None of the above


Identify the incorrect statement among the following:

  • There is a decrease in the radii of the atoms or ions as one proceeds from La to Lu.

  • Lanthanoid contraction is the accumulation of successive shrinkages

  • As a result of lanthanoid contraction, the properties of 4d series of the transition elements have no similarities with the 5d series of elements

  • As a result of lanthanoid contraction, the properties of 4d series of the transition elements have no similarities with the 5d series of elements


Advertisement
<

It is because of inability of ns2 electrons of the valence shell to participate in bonding that

  • Sn2+ is reducing while Pb4+ is oxidising

  • Sn2+ is oxidising while Pb4+ is reducing

  • Sn2+ and Pb2+ are both oxidising and reducing

  • Sn2+ and Pb2+ are both oxidising and reducing

1672 Views

Advertisement