Arrange the following compounds in increasing order of solubility in water:
C6H5NH2, (C2H5)2NH, C2H5NH2
The increasing order of solubility in water of the given compounds is as follows:
C6H5NH2 < (C2H5)2NH < C2H5NH2
The more extensive the hydrogen bonding, the higher is the solubility of the compound in water. C2H5NH2 contains two H-atoms, whereas (C2H5)2NH contains only one H-atom. Therefore, C2H5NH2 is more soluble than (C2H5)2NH. The solubility of C6H5NH2 is least due to its high molecular mass.
Out of SN1 and SN2, which reaction occurs with
(a) Inversion of configuration
(b) Racemisation