Stoichiometry And Stoichiometric Calculations | Some Basic Concepts Of Chemistry | Notes | Summary - Zigya

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Some Basic Concepts of Chemistry

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Stoichiometry And Stoichiometric Calculations

The word ‘stoichiometry’ is derived from two Greek words - stoicheion (meaning element) and metron (meaning measure).

Stoichiometry deals with the calculation of masses (sometimes volumes also) of the reactants and the products involved in a chemical reaction.

Limiting Reagent

The reactant which gets consumed first or limits the amount of product formed is known as limiting reagent.

In other words, The reactant which is present in the lesser amount gets consumed after some time and after that, no further reaction takes place whatever be the amount of the other reactant present. Hence, the reactant which gets consumed limits the amount of product formed and is, therefore, called the limiting reagent.

Reaction In Solution

The concentration of a solution or the amount of substance present in its given volume can be expressed in any of the following ways.

  1. Mass percent or weight percent (w/w %)
  2. Mole fraction
  3. Molarity
  4. Molality

  • Mass Per Cent

    Mass Percent is the mass of the solute in grams per 100 grams of the solution.

    Mass percent sign space of space the space solute space equals space fraction numerator Mass space of space the space solute over denominator Mass space of space the space solution end fraction space straight x space 100

    A 5 % solution of sodium chloride means that 5 g of NaCl is present in 100g of the solution.

    Volume percent is the number of units of volume of the solute per 100 units of the volume of solution.

    Volume space percent sign space of space the space solute space

equals space fraction numerator Volume space of space the space solute over denominator Volume space space of space the space solution end fraction space straight x space 100

    A 5 % (v/v) solution of ethyl alcohol contains 5 cm3 of alcohol in 100 cm3 of the solution.

  • Mole Fraction

    Mole Fraction is the ratio of a number of moles of one component to the total number of moles (solute and solvents) present in the solution. It is expressed as 'x'.

    Mole space fraction space of space the space solute space

equals space fraction numerator Moles space of space the space solute over denominator Moles space of space solute space plus space Moles space of space solvent end fraction

Mole space fraction space of space the space solvent

equals space fraction numerator Moles space of space the space solvent over denominator Moles space of space solute space plus space Moles space of space solvent end fraction

    Mole fraction of the solute + Mole fraction of solvent = 1

  • Molarity

    Molarity of the solution is defined as the number of moles of solute dissolved per litre (dm3) of the solution. It is denoted by the symbol M. Measurements in Molarity can change with the change in temperature because of solutions expand or contract accordingly.

    Molarity space of space the space solution space

equals space fraction numerator No. space of space moles space of space the space solute over denominator Volume space of space the space solution space in space litre end fraction space equals space straight n over straight V

    The Molarity of the solution can also be expressed in terms of mass and molar mass

    Molarity of the solution =

    fraction numerator Mass space of space the space solute over denominator Molar space mass space of space the space solute space straight x space volume space of space the space solution space in space litre end fraction

    In terms of weight, the molarity of the substance can be expressed as:

    Molarity space equals space fraction numerator Wg over denominator straight M space straight g space mol to the power of negative 1 end exponent space straight x space straight V space litre end fraction space equals space fraction numerator straight W over denominator straight M space straight X space straight V end fraction space mol divided by straight L

     

  • Molality

    Molality- Molality is defined as the number of moles of solute dissolved per 1000 g (1 kg) of solvent. Molality is expressed as 'm'.

    Molality space equals space fraction numerator Moles space of space the space solute over denominator Wt. space of space solvent space left parenthesis in space gm right parenthesis end fraction space straight x space 1000

     

     

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