Important Questions of Amines Chemistry | Zigya

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411.

State reasons for the following:

(i) pKb value for aniline is more than that for methylamine.

(ii) Ethylamine is soluble in water whereas aniline is not soluble in water.

(iii) Primary amines have higher boiling points than tertiary amines.
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412.

The conversion of primary aromatic amines into diazonium salts is known as __________ .

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413.

Account for the following:
(i) Primary amines (R-NH2) have higher boiling point than tertiary amines (R3N).
(ii) Aniline does not undergo Friedel - Crafts reactions:
(iii) (CH3)2NH is more basic than (CH3)3N in an aqueous solution.

OR

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414.

Give reasons:
Acetylation of aniline reduces its activation effect.

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415.

Give reasons :
CH3NH2 is more basic than C6H5NH2.

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416.

Give reasons :
Although –NH2 is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline.

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417.

Write the reactions involved in the following :

Diazotisation


418.

Write the reactions involved in the following :

Gabriel phthalimide synthesis


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419.

Give reasons:
(CH3)2NH is more basic than (CH3)3N in an aqueous solution.


420.

Give reasons:

Aromatic diazonium salts are more stable than aliphatic diazonium salts.


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