Giving a reason, arrange the following amines in order of decreasing basicity.
The correct order is:
The -I effect of F decreases the electron density of N atom and decreasing the basicity of amines. But the -I effect of F decrease as it moves always from the amine group and therefore increases the basicity.
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125.Write the conjugate acid and conjugate base of:
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126.
Complete the reaction: CH3NH2 + H2O →
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127.
Complete the reaction: CH3CHNH2 + HCl(g) →
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128.
How will you purify aniline containing non-basic impurities ?
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Long Answer Type
129.
Write the structure of the isomeric aromatic amines with formula C7H9N and give their IUPAC names.
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Short Answer Type
130.Write chemical equations for the following reactions: (i) Reaction of ethanolic NH3 with C2H5Cl.
(ii) Ammonolysis of benzyl chloride and reaction of amine so formed with two moles of CH3l.