Short Answer TypeWrite the structures of main products when aniline reacts with the following reagents:
(i) Br2 water
(ii) HCl
(iii) (CH3CO)2O/pyridine
Arrange the following in the increasing order of their boiling point: C2H5NH2, C2H5OH, (CH3)3N
Increasing order of boiling point: (CH3)3N < C2H5NH2 < C2H5OH
Alcohols have a higher boiling point as compared to that of amines because of oxygen, being more electronegative, forms strong hydrogen bond as compared to that of nitrogen. In tertiary amine, there is no hydrogen to form hydrogen bond and hence, has the lowest boiling point.Give a simple chemical test to distinguish between the following pair of compounds:
(CH3)2NH and (CH3)3N.
Arrange the following compounds in increasing order of solubility in water:
C6H5NH2, (C2H5)2NH, C2H5NH2
Arrange the following compounds in an increasing order of their solubility in water:
C6H5NH2, (C2H5)2NH, C2H5NH2
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