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601.

The following species generates a highly stable radical on exposure to 100 W bulb light. Which one of the following represents this stable radical?

  

  • Me2C°(CN)

  • C°H3

  • C°N

  • Me2C(CN)N=C°


A.

Me2C°(CN)

On photolytic cleavage, the diazo compounds produce free radicals, followed by loss of nitrogen.

 


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602.

Which of the following nitro compounds are not soluble in NaOH?

  • (CH3)3C-NO2

  • (CH3)2CH-NO2

  • CH3CH2-NO2

  • Ph-CH2-NO2


603.

The reaction,

R-CO-R H2SO4N3H RCONHR + N2 is called

  • Claisen-Schmidt reaction

  • Kolbe-Schmidt reaction

  • Schmidt reaction

  • Kolbe's reaction


604.

Which of the following compounds will give red colour on Lassaigne test?

  • NaCNS

  • NH2CSNH2 (thiourea)

  • p-NH2C6H4SO3H (p- aminobenzene sulphonic acid)

  • all of the above


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605.

A positive carbylamine test is given by

I. N, N-dimethylaniline

II. 2, 4-dimethylamine

III. N-methyl-o-methylaniline

IV. p-methylbenzyl amine

  • (II) and (IV)

  • (I) and (IV)

  • (II) and (III)

  • (I) and (II)


606.

Wat will be the final product of following reaction sequence?


607.

The IUPAC name of the following compound is

 

  • 2-carbamoylhexanal

  • 2-carbamoylhex-3-enal

  • 2-methyl-6-oxohex-3-enamide

  • 6-keto-2-methyl hexamide


608.

Which one of the following is the correct structure of sulphapyridine?


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609.

Iidentify Z in the following reaction:


610.

H3CCONH2 + Br2 + 4 NaOH  Y + Na2CO3+ 2NaBr + 2H2O

  • H3CCH2NH2

  • H3CNH2

  • H3CCOBr

  • HCONH2


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