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 Multiple Choice QuestionsMultiple Choice Questions

601.

The following species generates a highly stable radical on exposure to 100 W bulb light. Which one of the following represents this stable radical?

  

  • Me2C°(CN)

  • C°H3

  • C°N

  • Me2C(CN)N=C°


602.

Which of the following nitro compounds are not soluble in NaOH?

  • (CH3)3C-NO2

  • (CH3)2CH-NO2

  • CH3CH2-NO2

  • Ph-CH2-NO2


603.

The reaction,

R-CO-R H2SO4N3H RCONHR + N2 is called

  • Claisen-Schmidt reaction

  • Kolbe-Schmidt reaction

  • Schmidt reaction

  • Kolbe's reaction


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604.

Which of the following compounds will give red colour on Lassaigne test?

  • NaCNS

  • NH2CSNH2 (thiourea)

  • p-NH2C6H4SO3H (p- aminobenzene sulphonic acid)

  • all of the above


D.

all of the above

When nitrogen and sulphur both are present in the organic compound, they combine during fusion to form sodium thiocyanate (sulphocyanide). This when heated with FeSO4 or FeCl3, produces a red blood colouration due to ferric thiocyanate (or sulphocyanide). Thus, thiourea and p-aminobenzene sulphonic acid give red colour on lassaigne test.

Na + C + S + N  NaSCN(sodium thiocyanate or sodium sulphocyanide)Fe3+ + 3NaSCN  Fe(SCN)3ferric thiocyanate                             (ferric sulphocyanide)                             (blood red colouration)


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605.

A positive carbylamine test is given by

I. N, N-dimethylaniline

II. 2, 4-dimethylamine

III. N-methyl-o-methylaniline

IV. p-methylbenzyl amine

  • (II) and (IV)

  • (I) and (IV)

  • (II) and (III)

  • (I) and (II)


606.

Wat will be the final product of following reaction sequence?


607.

The IUPAC name of the following compound is

 

  • 2-carbamoylhexanal

  • 2-carbamoylhex-3-enal

  • 2-methyl-6-oxohex-3-enamide

  • 6-keto-2-methyl hexamide


608.

Which one of the following is the correct structure of sulphapyridine?


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609.

Iidentify Z in the following reaction:


610.

H3CCONH2 + Br2 + 4 NaOH  Y + Na2CO3+ 2NaBr + 2H2O

  • H3CCH2NH2

  • H3CNH2

  • H3CCOBr

  • HCONH2


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