Which of the following will most stable diazonium salt RN2+X-?
CH3N2+X-
C6H5N2+X-
CH3CH2N2+X-
CH3CH2N2+X-
Nitrobenzene on reaction with conc. HNO3/H2SO4 at 80-1000C forms which one of the following products?
1,2-dinitrobenzene
1,3- dinitrobenzene
1,4-dinitrobenzene
1,4-dinitrobenzene
Some meta-directing substituents in aromatic substitution are given. Which one is most deactivating?
-CN
-SO3H
-COOH
-COOH
Which of the following compounds will not undergo Friedel -Craft's reaction easily?
Cumene
Xylene
Nitrobenzene
Nitrobenzene
In the reaction,
HgSO4/H2SO4
Cu2Cl2
H3PO2 and H2O
H3PO2 and H2O
C.
H3PO2 and H2O
When diazonium salt is treated with H3PO2 followed by hydrolysis. It diazonium group is replaced by -H resulting to the formation of hydrocarbon. Thus, A must be H3PO2/H2O.
Among the following compounds, the one that is most reactive towards electrophilic nitration is
Benzoic acid
Nitrobenzene
toluene
toluene
Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne?
NaNH2
HCl
O2
O2
Consider the reaction,
RCHO +NH2NH2 →RCH =N-NH2
What sort of reaction is it?
Electrophilic addition elimination reaction
Free radical addition-elimination reaction
Electrophilic substitution elimination reaction
Electrophilic substitution elimination reaction
An organic compound (C3H9N) (A), when treated with nitrous acid, gave an alcohol and N2 gas was evolved. (A) on warming with CHCl3 and Caustic potash gave (C) which on reduction gave iso-propyl methylamine predict the structure of (A)
CH3-CH2 -NH -CH3