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641.

Method by which aniline cannot be prepared is 

  • hydrolysis phenyl isocyanide with the acidic solution

  • degradation of benzamide with bromine in alkaline solution

  • reduction of nitrobenzene with H2/Pd in ethanol

  • reduction of nitrobenzene with H2/Pd in ethanol


D.

reduction of nitrobenzene with H2/Pd in ethanol

Due to resonance in chlorobenzene C- Cl  bond accquires double bond chracter hence, C -Cl bond is inert towards nucleophile (phthalimide ion)

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642.

Which of the following compound is most basic?

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643.

The following reaction, 


is known by the name

  • Friedel -Crafts reaction

  • Perkins reaction

  • Acetylation reaction

  • Acetylation reaction

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644.

Which of the following statements about primary amines is false?

  • Alkyl amine are stronger bases than aryl amines

  • Alkyl amines reacts with nitrous acid to produce alcohols

  • Aryl amines react with nitrous acid to produce phenols

  • Alkyl amines are stronger base than ammonia


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645.

Predict the product,


 

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646.

In a reaction of aniline, a coloured product C was obtained.

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647.

Which one of the following on reduction with lithium aluminium hydride yield a secondary amine?

  • Nitroethane

  • Methylisocyanide

  • Acetamide

  • Acetamide


648.

Which of the following is more basic than aniline?

  • Diphenylamine

  • Triphenylamine

  • p-nitroaniline

  • p-nitroaniline

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649.

The correct increasing order of basic strength for the following compounds is 

  • II < III < I 

  • III < I < II

  • III < II < I

  • III < II < I

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650.

Which of the following reactions is appropriate for converting acetamide to methanamine?

  • Carbylamine reaction

  • Hoffmann hypobromamide reaction

  • Stephens reaction

  • Stephens reaction

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