The compound which on reaction with aqueous nitrous acid at low temperature produces an oily nitrosoamine is
methyl amine
ethyl amine
diethyl amine
triethyl amine
Hofmann's bromamide reaction is used to convert :
acid to alcohol
alcohol to acid
amide to amine
amine to amide
Compound A (molecular formula C3H8O) is treated with acidified potassium dichromate to form a product B (molecular formula C3H6O). B forms a shining silver mirror on warming with ammoniacal silver nitrate. B when treated with an aqueous solution of H2NCONHNH2. HCl and sodium acetate gives a product C. Identify the structure of C.
CH3CH2CH=NNHCONH2
CH3-C(CH3)=NNHCONH2
CH3-C(CH3)=NCONHNH2
CH3CH2CH=NCONHNH2
A.
CH3CH2CH=NNHCONH2
A is an alchohol and its oxidation product gives Tollen's test.Tollen's reagents is a chemical reagents used to determine the presence of aldehyde, aromatic aldehyde, and alpha-hydroxyl ketone functional group. The reagent consists of a solution of sliver nitrate, ammonia and some sodium hydroxide.
Reaction of B indicates that B is an aldehyde thus B should be C2H5CHO or CH3CH2CHO and therefore C should be CH3CH2CH=NNHCONH2.
Which of the following fibres is not made up of polyamides ?
Wool
Natural silk
Artificial silk
Nylon
The high oxidising power offluorine is due to :
high electron affinity
high heat of dissociation and low heat of hydration
high heat of hydration and low heat of dissociation
high heat of hydration and high heat of dissociation
Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotised and thenheated with cuprous bromide. The reaction mixture so formed contains
mixture of o- and m-bromotoluenes
mixture of o- and p-bromotoluenes
mixture of o- and p-dibromobenzenes
mixture of o- and p-bromoanilines
The reaction of an organic compound with ammonia followed by nitration of the product gives a powerful explosive called ROX.The organic compound is
phenol
toluene
glycerine
formaldehyde
In the following sequence of the reactions, what is D ?
Primary amine
An amide
Phenyl isocyanate
A chain lengthed hydrocarbon