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 Multiple Choice QuestionsMultiple Choice Questions

741.

Benzene diazonium chloride on reaction with phenol in weakly basic medium gives

  • diphenyl ether

  • p-hydroxy azobenzene

  • chlorobenzene

  • benzene


742.

Hinsberg's reagent is

  • C6H5COCl

  • CH3COCl

  • C6H5CH2Cl

  • C6H5SO2Cl


743.

Nessler's reagent is used to detect

  • CrO42-

  • PO43-

  • MnO4-

  • NH4+


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744.

The correct order of the basic strength of methyl substituted amines in aqueous solution is :

  • (CH3)3N > CH3NH2 > (CH3)2NH

  • (CH3)3N > (CH3)2NH> CH3NH2

  • CH3NH> (CH3)2NH >(CH3)3

  • (CH3)2NH> CH3NH> (CH3)3N


D.

(CH3)2NH> CH3NH> (CH3)3N

In aqueous solution, electron donating inductive effect, solvation effect (H-bonding) and steric hindrance all together affect basic strength of substituted amines.
Basic character :

(CH3)2NH> CH3NH> (CH3)3N

   1°            2°              3°


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