Using the orbital overlap concept, explain the formation of:(i)�

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 Multiple Choice QuestionsLong Answer Type

151.

Discuss the orbital shapes of the following covalent molecules:
(i) HF (ii) H2O (iii) NH3.

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 Multiple Choice QuestionsShort Answer Type

152.

Why is a sigma bond stronger than pi bond ?

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153.

Why are lone pair-lone pair repulsion stronger than lone pair-bond pair.

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 Multiple Choice QuestionsLong Answer Type

154.

Describe, in brief, the types of covalent bonds ?

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155.

Using the orbital overlap concept, explain the formation of:
(i) O2 molecule            (ii) N2 molecule.


 (i) O2 molecule: The electronic configuration of oxygen atom
(z = 8) is 
It has two half filled 2p-orbitals in its valence shell. In the formation of the oxygen molecule. One of the two half filled 2p-orbitals of each oxygen atom overlaps mutually along the internuclear axis to form σ bond. The other half-filled 2p orbitals of each oxygen atom undergo sidewise overlapping to form -bond.
Thus, two oxygen atoms are linked together by a double bond, one of which is sigma bond and other is  a bond. 



(ii) N
2 molecule. The electronic configuration of nitrogen atom (Z = 7) is
 It has three half filled 2p-orbitals in its valence shell. In the formation of the nitrogen molecule, one of the three half-filled 2p orbitals of each nitrogen atom overlaps mutually along the internuclear axis to form a bond. The other two 2p-half filled orbitals of a nitrogen atom undergo sidewise overlapping with their parallel oriented 2p-orbitals of other nitrogen to form two  bonds. Thus, two nitrogen atoms are linked together by a triple bond, one of which is sigma bond and the other two are  bonds.


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156.

Distinguish between a sigma open parentheses straight sigma close parentheses bond and a pi space left parenthesis straight pi right parenthesis bond.

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157.

What do you mean by: (i) Bond length  (ii) Bond enthalpy   (iii) Bond order?

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158.

What is coordinate or dative bond? Explain the formation of the bond with some examples.

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 Multiple Choice QuestionsShort Answer Type

159.

What are the conditions for co-ordinate bonding?

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 Multiple Choice QuestionsLong Answer Type

160.

What are physical important characteristics of coordinate compounds?

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