Explain coordinate bond by the orbital concept. from Chemistry

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161.

Explain coordinate bond by the orbital concept.


A coordinate bond is formed by the overlapping of an orbital of an atom containing a lone pair of electrons with the empty orbital of the other atom.
Let us consider the formation of ammonium ion (N+H4). It is formed by the combination of ammonia molecule and hydrogen ion.


The central nitrogen atom of ammonia molecule has one orbital containing a lone pair of electrons while the other three orbitals are filled up with bond pairs of electrons.
On the other hand, hydrogen ion has empty is orbital. When the Hion approaches ammonia molecule, its empty orbital overlaps the orbital of nitrogen atom containing a lone pair to form a dative bond. 

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162.

Differentiate between a covalent bond and co-ordinate bond.

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 Multiple Choice QuestionsShort Answer Type

163.

What do you understand by geometry and shapes of molecules?

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164.

Why do covalent moleucles have definite geometery?

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165.

Name the theory responsible for the definite geometry of covalent molecules. Give main features of the theory ?

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166.

What do you mean by Regular geometry and Irregular or Distorted geometry?

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167.

How will you explain the following order of the repulsive interactions between pair of electrons on the central atom:
Lone pair - Lone pair > Lone pair - Bond pair > Bond pair - Bond pair. 

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 Multiple Choice QuestionsLong Answer Type

168.

On the basis of VSEPR theory, discuss the geometry of the following covalent molecules: (i) BeF(ii) BF(iii) CH4.

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169.

With the help of VSEPR theory, explain the shape of: (i) NH3    (ii) H2O.

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 Multiple Choice QuestionsShort Answer Type

170.

Although geometries of NH3 and H2O molecules are distorted tetrahedral, the bond angle in water is less than that of ammonia. Discuss.

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