According to MO theory which of the following lists ranks the ni

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 Multiple Choice QuestionsMultiple Choice Questions

671.

Which of the following structures is the most preferred and hence of lowest energy of SO3

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672.

In which of the following pairs, both the species are not isostructural?

  • SiCl4.PCl4+

  • Diamond, carbide

  • NH3, PH3

  • NH3, PH3

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673.

In which of the following pairs of molecules/ions, the central atoms have sp2 hybridization?

  • NO2- and NH3

  • BF3 and NO2-

  • NH2- and H2O

  • NH2- and H2O

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674.

Which one of the following species does not exist under normal conditions?

  • Be2+

  • Be2

  • B2

  • B2

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675.

In which one of the following species the central atom has the type of hybridisation which si not the same as that present in the other three? 

  • SF4

  • I3-

  • SbCl52-

  • SbCl52-

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676.

The correct order of the decreasing ionic radii among the following isoelectronic species is

  • Ca2+ > K+ >S2- > Cl-

  • Cl- > S2- > Ca2+ > K+

  • S2- > Cl- > K+ > Ca2+

  • S2- > Cl- > K+ > Ca2+

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677.

In which of the following molecules the central atom does not have sp3 hybridisation?

  • CH4

  • SF4

  • BF4-

  • BF4-

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678.

From the following bond energies:

H-H bond energy: 431.37 kJ mol-

C=C  bond energy: 606.10 kJ mol-

C- C bond energy: 336.49 kJ mol-

C-H bond energy: 410.50 kJ mol-

Enthalpy for the reaction,


will be


  • 1523.6 kJ  mol-

  • -243.6 kJ mol-

  • -1200. kJ mol-

  • -1200. kJ mol-

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679.

According to MO theory which of the following lists ranks the nitrogen species in terms of increasing bond order?

  • straight N subscript 2 superscript minus space less than space straight N subscript 2 space less than space straight N subscript 2 superscript 2 minus end superscript
  • straight N subscript 2 superscript 2 minus end superscript less than space straight N subscript 2 superscript minus space less than space straight N subscript 2
  • straight N subscript 2 space less than space straight N subscript 2 superscript 2 minus end superscript space less than straight N subscript 2 superscript minus
  • straight N subscript 2 space less than space straight N subscript 2 superscript 2 minus end superscript space less than straight N subscript 2 superscript minus


A.

straight N subscript 2 superscript minus space less than space straight N subscript 2 space less than space straight N subscript 2 superscript 2 minus end superscript

Bond Order = ><br>Where <br>N<sub>b</sub> = number of electrons in bonding MO<br><br>N<sub>a</sub> = number of electrons in antibonding MO<br><br><br><img class=

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680.

The state of hybridization of C2, C3, C5 and C6 of the hydrocarbon,


is in the following sequence

  • sp, sp3, sp2 and sp3

  • sp3, sp2, sp2 and sp

  • sp,sp2,sp2 and sp3

  • sp,sp2,sp2 and sp3

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