Assertion : cis-3-chloroprop-2-enoic acid is less stable tha

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801.

Assertion : cis-3-chloroprop-2-enoic acid is less stable than its trans-form.

Reason : Dipole moment of cis-form is greater than trans- form.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


B.

If both assertion and reason are true but reason is not the correct explanation of assertion.

For acrylic systems, trans-isomers are more stable than cis-isomers. This is due to increased unfavourable steric interaction of the substituents in cis-isomer.

Dipole moment of trans-form is zero (or less) depending whether the substituents on both sides of double bond are same or not while cis-forms are polar in nature with certain value of dipole moment.


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802.

Assertion : Diamond and graphite do not have the same crystal structure.

Reason : Diamond is crystalline while graphite is amorphous.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


803.

Assertion : ClFhas T-shape structure.

Reason : It has two lone pairs arranged at 180° angle.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false


804.

Assertion : Ois paramagnetic.

Reason : It has one unpaired electron.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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805.

Decreasing order of bond angle is

  • BeCl2 > NO2 > SO2

  • BeCl2 > SO2 > NO2

  • SO2 > BeCl2 > NO2

  • SO2 > NO2 > BeCl2


806.

In the ground state of Cu2+ the number of shells occupied, subshells occupied, filled orbitals and unpaired electrons respectively are

  • 4, 8, 15 0

  • 3, 6, 15, 1

  • 3, 6, 14, 0

  • 4, 7, 14, 2


807.

CaO and NaCl have the same crystal structure and approximately the same ionic radii. If U is the lattice energy ofNaCI, the approximate lattice energy of CaO is

  • U/2

  • U

  • 2U

  • 4U


808.

During the formation of a chemical bond :

  • electron-electron repulsion becomes more than the nucleus-electron attraction

  • energy of the system does not change

  • energy increases

  • energy decreases


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809.

The number of σ- and π-bonds present in pent-4-ene-1-yne is

  • 10, 3

  • 4, 9

  • 3, 10

  • 9, 4


810.

Assertion : H2S is less acidic than H2Te.

Reason : Te has larger, radius than S.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


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