Assertion : cis-3-chloroprop-2-enoic acid is less stable than its trans-form.
Reason : Dipole moment of cis-form is greater than trans- form.
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If assertion is true but reason is false.
If both assertion and reason are false.
Assertion : Diamond and graphite do not have the same crystal structure.
Reason : Diamond is crystalline while graphite is amorphous.
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Assertion : ClF3 has T-shape structure.
Reason : It has two lone pairs arranged at 180° angle.
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If assertion is true but reason is false.
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Assertion : O2 is paramagnetic.
Reason : It has one unpaired electron.
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If assertion is true but reason is false.
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Decreasing order of bond angle is
BeCl2 > NO2 > SO2
BeCl2 > SO2 > NO2
SO2 > BeCl2 > NO2
SO2 > NO2 > BeCl2
In the ground state of Cu2+ the number of shells occupied, subshells occupied, filled orbitals and unpaired electrons respectively are
4, 8, 15 0
3, 6, 15, 1
3, 6, 14, 0
4, 7, 14, 2
CaO and NaCl have the same crystal structure and approximately the same ionic radii. If U is the lattice energy ofNaCI, the approximate lattice energy of CaO is
U/2
U
2U
4U
D.
4U
Lattic energy =where q1 and q2 are charges on ions and r is the distance between them. Since interionic distances in CaO and NaCl are similar, (larger cation has smaller anion and vice versa) therefore, r is almost the same. Therefore, lattice energy depends only on charge. Since the magnitude of charge on Na+ and Cl-ions is unity and that on Ca2+ and O2- ions is 2 each, therefore, the lattice energy of CaO is four times the lattice energy of NaCl, i.e..4U.
During the formation of a chemical bond :
electron-electron repulsion becomes more than the nucleus-electron attraction
energy of the system does not change
energy increases
energy decreases
Assertion : H2S is less acidic than H2Te.
Reason : Te has larger, radius than S.
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