Assertion : The free gaseous Cr atom has six unpaired electrons.R

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851.

The statement true for N3- is

  • it has a non-linear structure

  • it is called pseudohalogen

  • the formal oxidation state of nitrogen in this anion is -1

  • it is isoelectronic with NO2


852.

Which of the following molecule has highest bond energy ?

  • F-F

  • N-N

  • C-C

  • O-O


853.

Shape of O2F2 is similar to that of

  • C2F2

  • H2O2

  • H2F2

  • C2H2


854.

The ONO angle is maximum in

  • NO3-

  • NO2-

  • NO2

  • NO2+


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855.

The number of σ and π bonds present in pent-4-ene, I-yne is :

  • 10 , 3

  • 4 , 9

  • 3 , 10

  • 9 , 4


856.

The dipole moment is the highest for

  • trans-2-butene

  • 1,3-dimethylbenzene

  • acetophenone

  • ethanol.


857.

Which of the following are arranged in the decreasing order of dipole moment?

  • CH3Cl, CH3Br, CH3F

  • CH3Br, CH3Cl, CH3F

  • CH3Cl, CH3Br, CH3F

  • CH3Br, CH3F, CH3Cl


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858.

Assertion : The free gaseous Cr atom has six unpaired electrons.

Reason: Half-filled s orbital has greater stability.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


C.

If assertion is true but reason is false

Cr24 [Ar] 3d4 4s2Cr [Ar] 3d54s1

Half-filled d-orbital has greater stability.


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859.

Assertion : All F- S -F angle in SF4 is greater than 90° but less than 180°.

Reason : The lone pair-bond pair repulsion is weaker than bond pair-bond pair repulsion.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


860.

Which of the following compounds possesses the C-H bond with the lowest bond dissociation energy?

  • Toluene

  • Benzene

  • n-Pentane

  • 2,2-Dimethylpropane


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