Important Questions of Chemical Kinetics Chemistry | Zigya

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601.

For the reaction 

2A + B → 3C + D

Which of the following does not express the reaction rate?

  • fraction numerator straight d left square bracket straight C right square bracket over denominator 3 dt end fraction
  • negative fraction numerator straight d left square bracket straight B right square bracket over denominator dt end fraction
  • fraction numerator straight d left square bracket straight D right square bracket over denominator dt end fraction
  • fraction numerator straight d left square bracket straight D right square bracket over denominator dt end fraction
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602.

Consider the reaction

N2 (g) + 3 H2 (g) → 2 NH3 (g) 

The equality relationship between fraction numerator straight d left square bracket NH subscript 3 right square bracket over denominator dt end fraction space and space fraction numerator negative straight d left square bracket straight H subscript 2 right square bracket over denominator dt end fraction is:

  • fraction numerator straight d left square bracket NH subscript 3 right square bracket over denominator dt end fraction space equals space minus space 1 third fraction numerator straight d left square bracket straight H subscript 2 right square bracket over denominator dt end fraction
  • fraction numerator straight d left square bracket NH subscript 3 right square bracket over denominator dt end fraction space equals space minus space 2 over 3 fraction numerator straight d left square bracket straight H subscript 2 right square bracket over denominator dt end fraction
  • plus fraction numerator straight d left square bracket NH subscript 3 right square bracket over denominator dt end fraction space equals space minus 3 over 2 fraction numerator straight d left square bracket straight H subscript 2 right square bracket over denominator dt end fraction
  • plus fraction numerator straight d left square bracket NH subscript 3 right square bracket over denominator dt end fraction space equals space minus 3 over 2 fraction numerator straight d left square bracket straight H subscript 2 right square bracket over denominator dt end fraction
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603.

Which one of the following statements is not correct?

  • Catalyst does not initiate any reaction

  • The value of equilibrium constant is changed in the presence of a catalyst in the reaction at equilibrium

  • Enzymes catalyse mainly bio-chemical reactions

  • Enzymes catalyse mainly bio-chemical reactions

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604.

A first-order reaction has a specific reaction rate of 10–2 s–1. How much time will it take for 20 g of the reactant to reduce to 5 g?

  • 238.6 second

  • 138.6 second

  • 346.5 second

  • 346.5 second

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605.

The equilibrium constants of the following are.

straight N subscript 2 space plus space 3 straight H subscript 2 space rightwards harpoon over leftwards harpoon with space on top space 2 NH subscript 3 space space straight K subscript 1
straight N subscript 2 space plus space straight O subscript 2 space rightwards harpoon over leftwards harpoon with space on top space 2 NO space space space space straight K subscript 2
straight H subscript 2 space plus space 1 half straight O subscript 2 space rightwards arrow with space on top space straight H subscript 2 straight O space straight K subscript 3

The equilibrium constant (K) of the reaction:

2 NH subscript 3 space plus space 5 over 2 straight O subscript 2 space rightwards harpoon over leftwards harpoon with straight K on top space 2 NO space plus space straight H subscript 2 straight O comma space will space be

  • straight K subscript 1 straight K subscript 3 superscript 3 divided by straight K subscript 2
  • straight K subscript 2 straight K subscript 3 superscript 3 space divided by space straight K subscript 1
  • straight K subscript 2 straight K subscript 3 superscript 3 space divided by space straight K
  • straight K subscript 2 straight K subscript 3 superscript 3 space divided by space straight K
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606.

A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H2SO4. The evolved gaseous mixture is passed through KOH pellets. Weight (in gram) of the remaining product at STP will be

  • 1.4

  • 3.0

  • 4.4

  • 2.8


607.

The correct difference between first and second order reactions is that

  • The rate of a first-order reaction does not depend on reactant concentrations; the rate of a second-order reaction does depend on reactant concentrations

  • The half-life of a first-order reaction does not depend on [A]0; the half-life of a second-order reaction does depend on [A]0

  • The rate of a first-order reaction does depend on reactant concentrations; the rate of a second-order reaction does not depend on reactant concentrations

  • A first-order reaction can catalyzed; a second-order reaction cannot be catalyzed


608.

When initial concentration of the reactant is doubled, the half-life period of a zero order reaction

  • Is halved

  • Is doubled

  • Remains unchanged

  • Is tripled


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609.

For the chemical reaction,

2O3 ⇌ 3O2

The reaction proceeds as follows

O3 ⇌ O2 + O

O + O3 → 2O2 (slow)

The rate law expression will be

  • r = k' [O3]2

  • r = k' [O3]2[O2]-1

  • r = k'[O3][O2]

  • unpredictable


610.

In the following graph

The slope of line AB give the information of the

  • value of Ea2.303

  • Value of 2.303Ea

  • value of -Ea2.303

  • value of -Ea2.303 RT


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