The conversion of molecules X to Y follows second order kinetics.

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 Multiple Choice QuestionsShort Answer Type

1. For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M is 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
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4. The conversion of molecules X to Y follows second order kinetics. If concentration of X is increased to three times how will it affect the rate of formation of Y?


Let the reaction is X →Y

This reaction follows second order kinetics.
So that, the rate equation for this reaction will 
Rate, R = k[X]2 .............(1)
Let initial concentration is x mol L−1,
Plug the value in equation (1)
Rate, R1 = k .(a)2
= ka2
Given that concentration is increasing by 3 times so new concentration will 3a mol L−1
Plug the value in equation (1) we get 
Rate, R2 = k (3a)2
= 9ka2
We have already get that R1 = ka2 plus this value we get
R2 = 9 R1 
So that, the rate of formation will increase by 9 times.
Rate = k[A]2
If concentration of X is increased to three times,
Rate = k[3A]2
or Rate = 9 k A2
Thus, rate will increase 9 times.

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5. A first order reaction has a rate constant 1.15 x 10–3 s–1. How long will 5 g of this reactant take to reduce to 3 g?
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6. Time required to decompose SO2 Cl2 to half its initial amount is 60 minutes. If the decomposition is a first order reaction, calculate the rate constant of the reaction.
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7. What will be the effect of temperature on rate constant?
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 Multiple Choice QuestionsLong Answer Type

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 Multiple Choice QuestionsShort Answer Type

9.

The activation energy for the reaction
2HI (g) → H2 + I2(g)
is 209.5 kJ mol–1 at 581 k. Calculate the fraction of molecules of reactants having energy equal to or greater than activation energy?

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What is the order of the reaction?
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