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 Multiple Choice QuestionsShort Answer Type

1. For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M is 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
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2. In a reaction 2A → Products, the concentration of A decreases from 0.5 mol to 0.4 mol L–1 in 10 minutes. Calculate the rate during this interval.
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3. For a reaction, A + B → Product; the rate law is given by, r = k[ A]1/2 [B]2. What is the order of reaction?
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4. The conversion of molecules X to Y follows second order kinetics. If concentration of X is increased to three times how will it affect the rate of formation of Y?
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5. A first order reaction has a rate constant 1.15 x 10–3 s–1. How long will 5 g of this reactant take to reduce to 3 g?
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6. Time required to decompose SO2 Cl2 to half its initial amount is 60 minutes. If the decomposition is a first order reaction, calculate the rate constant of the reaction.


Given that
half life, t
1/2 = 60 min = 60 x 60 = 3600 sec (1 min = 60 sec)
The formula of half life for the a 1st order

reaction,
For a first order reaction.


t = 2.303k log 1a-xt1/2 = 60 minutes         = 60 × 60 sec. = 360 sec.   k = 0.6933600 sec. = 1.925 × 10-4 s-1
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7. What will be the effect of temperature on rate constant?
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 Multiple Choice QuestionsLong Answer Type

8. The rate of the chemical reaction doubles for an increase of 10 k in absolute temperature from 298 K. Calculate Ea.
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 Multiple Choice QuestionsShort Answer Type

9.

The activation energy for the reaction
2HI (g) → H2 + I2(g)
is 209.5 kJ mol–1 at 581 k. Calculate the fraction of molecules of reactants having energy equal to or greater than activation energy?

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10. For the reaction A B, the rate of reaction becomes twenty seven times when the concentration of A is increased three times.
What is the order of the reaction?
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