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 Multiple Choice QuestionsShort Answer Type

111. The gas phase decomposition of acetaldehyde.
CH3CHO(g)   CH4(g) + CO(g)

at 680 K is observed to follow the rate expression.

Rate-dCH3CHOdt = kCH3CHO3/2

If the rate of decomposition is followed by monitoring the partial pressure of the acetaldehyde we can express the rate as

-dPCH3CHOdt = kPCH3 CHO3/2

If the pressure is measured in atmosphere and time in minutes, then
(a) What are the units of the rate of reaction?
(b) What are the units of rate constant k?
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112.

(a) Show graphically how the rate of first order reaction vary with only one reactant depends concentration of reactant.
(b) Give one example of first order reaction.

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113. Suggest explainations for:
The increased speed of a simple bimolecular change when temperature of the reaction mixture is increased.
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114. Suggest explainations for:
The action of a solid phase catalyst to increase the rate of unimolecular gas—phase decomposition reaction.
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115. Suggest explainations for:
One gram of pulverized wood burns faster than one gram piece of wood.
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 Multiple Choice QuestionsLong Answer Type

116.

(i) Define specific reaction rate.
(ii) Define Half-life period of a chemical reaction. Also obtain the expression for half-life period.

Or

Derive the general for of the expression for the half-life of a first order reaction.

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 Multiple Choice QuestionsShort Answer Type

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117. How can the rate of a fast reaction be determined by Flash Photolysis?


Flash photolysis: When we pass a powerful flash of short duration or laser beam, through the reaction mixture to initiate a reaction the atoms, ions or free radicals are formed.
These atoms, ions or free radicals formed can be identified by passing a second, Flash of light through the mixture immediately after the first flash.
For this the absorption spectrum of the mixture is monitored continuously at small regular intervals after first flash and the changes in the spectrum with time indicate the various processes occurring in the system.
It can also be studied by observing some other property like electrical conductance or magnetic property of the reaction mixture.

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118. How does temperature affect the rate of a reaction? Is there a corresponding equal decrease in number of collisions among molecules of a gaseous reaction? How is this effect explained by the concept of activation energy?
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119. Nitric oxide reacts with hydrogen to give nitrogen and water:

2NO+2H2  N2+2H2O

The kinetic of this reaction is explained by the following steps:

(i) 2NO + H2 → N2 + H2O2 (slow)
(ii) H2O2+ H2 → 2H2O  (fast)
What is the predicted law?

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120. Nitrogen dioxide reacts with fluorine to give

2NO2+F2  2NO2F

The kinetic of this reaction is explained by the following steps.

(i) NO2 + F→ 2NO2F (slow)
(ii) NO2 + F → NO2F (fast)

What is the predicted law?
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