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 Multiple Choice QuestionsShort Answer Type

51.

As the atomic number increases, the ionisation enthalpy _________ (in a period).

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52.

Which elements occupy the maxima of ionisation potential curve?

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53. Do elements have negative ionisation enthalpy?
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54.

The first ionisation enthalpies in electron volts of nitrogen and oxygen atoms are respectively given by:
(i) 14.6, 13.6            
(ii) 13.6, 14.6
(iii) 13.6, 13.6          
(iv) 14.6, 14.6

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55.

Al atom loses electrons successively to form Al+, Al2+ and Al3+ ions. Which step will have highest ionsiation enthalpy?

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56.

Arrange the following in decreasing negative electron gain enthalpy: B, C, N, O.

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57.

What is the electron gain enthalpy of neon?

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58.

The size of isoelectronic species: F-, Ne and Na+ is affected by:
(a) nuclear charge (Z)
(b) valence principal quantum number (n)
(c) electron-electron interaction in the outer orbitals.
(d) none of the factors because their size in the same.


(a) nuclear charge (Z). Isoelectronic species are the species belonging to different atoms or ions which have same number of electrons but different magnitudes of nuclear charges.

The size of an isoelectronic species increases with a decrease in the nuclear charge (Z). For example, the order of the increasing nuclear charge of F, Ne, and Na+ is as follows:

       F < Ne < Na+

Z     9     10     11

Therefore, the order of the increasing size of F, Ne and Na+ is as follows:

Na+ < Ne < F

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59.

From the electronic configuration of the elements A, B and C given below:
space space straight A space colon space 1 straight s squared space 2 straight s squared space 2 straight p subscript straight x superscript 1 space space 2 straight p subscript straight y superscript 1
space space straight B thin space colon space 1 straight s squared space 2 straight s squared space 2 straight p subscript straight x superscript 2 space 2 straight p subscript straight y superscript 1 space 2 straight p subscript straight z superscript 1
space space straight C thin space colon space 1 straight s squared space 2 straight s squared space 2 straight p subscript straight y superscript 1 space 2 straight p subscript straight z superscript 1
(i) Which one has least negative electron gain enthalpy and
(ii) Which one has highest ionisation enthalpy value?

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60.

Are the oxidation state and covalency of Al in open square brackets AlCl left parenthesis straight H subscript 2 straight O right parenthesis subscript 6 close square brackets to the power of 2 plus end exponent same?

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