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 Multiple Choice QuestionsLong Answer Type

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161.

A, B, C are three elements, B is an inert gas element other than helium; with this information, complete the table given below:

Element Atomic No. No. of electrons in the valence shell Group to which element belongs
A Z - 1    
B Z    
C Z+1    

Also, explain the following:
(i) Electron gain enthalpy of element A has large negative value than that of C.

(ii) Ionisation enthalpy of element C is less than that of A.

(iii) Electron gain enthalpy of B is positive.


Let B be an inert gas element neon with atomic number Z=10. Therefore, atomic number of A=9 (halogen) and of C=11 (alkali metal).
The electronic configuration of elements are:

Groups:
Element A belongs to Group 17 (Halogens).
Element B belongs to Group 18 (Noble gases).
Element C belongs to Group 11 (Alkali metals).

(i) Electron gain enthalpy of element A has large negative value than that of C. The element A (fluorine) requires only one electron to have a noble gas configuration. Thus, electron gain enthalpy of A is much more than that of C (sodium).

(ii) Ionisation enthalpy of C is less than that of A. The atomic size of A is smaller (atomic radius = 71 pm) than that of C (atomic radius = 154 pm).Thus, it is easier to remove an electron from C as compared to A. Hence ionisation enthalpy of C is less than that of B.

(iii) Electron gain enthalpy of B is positive. B being a noble gas element has a symmetrical electronic configuration ( 1s-2s22p6). Added electron has to enter the next higher principal quantum level leading to the positive value of electron gain enthalpy.

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162.

Define electronegativity. Explain the factors influencing electronegativity. How does it vary along periods and groups? what are its units?

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163.

What is the importance of electronegativity?

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 Multiple Choice QuestionsShort Answer Type

164.

Explain giving various reasons for the variation of electronegativity along a period and along a group.

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 Multiple Choice QuestionsLong Answer Type

165.

What is the basic difference between the terms electronegativity and electron gain enthalpy?

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 Multiple Choice QuestionsShort Answer Type

166.

How would you react to the statement that the electronegativity of N on Pauling scale is 3.0 in all the nitrogen compounds? 

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 Multiple Choice QuestionsLong Answer Type

167.

Give a brief account of valence ?

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168.

The valence of representative elements is either equal to the number of valence electrons or eight minus the number. What is the basis of their rule?

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 Multiple Choice QuestionsShort Answer Type

169.

Predict the formulae of the stable binary compounds that would be formed by the following pairs of elements:

silicon and oxygen


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170.

Predict the formulae of the stable binary compounds that would be formed by the following pairs of elements:
aluminium and bromine

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